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Novel Platinum-Porphyrin as Sensing Compound for Efficient Fluorescent and Electrochemical Detection of H2O2
- Source :
- Chemosensors, Volume 8, Issue 2, Chemosensors, Vol 8, Iss 29, p 29 (2020)
- Publication Year :
- 2020
- Publisher :
- Multidisciplinary Digital Publishing Institute, 2020.
-
Abstract
- Metalloporphyrins are highly recognized for their capacity to act as sensitive substances used in formulation of optical, fluorescent, and electrochemical sensors. A novel compound, namely Pt(II)-5,10,15,20-tetra-(4-allyloxy-phenyl) porphyrin, was synthesized by metalation with PtCl2(PhCN)2 of the corresponding porphyrin base and was fully characterized by UV-vis, fluorimetry, FT-IR, 1H-NMR, and 13C-NMR methods. The fluorescence response of this Pt-porphyrin in the presence of different concentrations of hydrogen peroxide was investigated. Besides, modified glassy carbon electrodes with this Pt-porphyrin (Pt-Porf-GCE) were realized and several electrochemical characterizations were comparatively performed with bare glassy carbon electrodes (GCE), in the absence or presence of hydrogen peroxide. The Pt-porphyrin demonstrated to be a successful sensitive material for the detection of hydrogen peroxide both by fluorimetric method in a concentration range relevant for biological samples (1.05&ndash<br />3.9 &times<br />10&minus<br />7 M) and by electrochemical method, in a larger concentration range from 1 &times<br />6 M to 5 &times<br />5 M. Based on different methods, this Pt-porphyrin can cover detection in diverse fields, from medical tests to food and agricultural monitoring, proving high accuracy (correlation coefficients over 99%) in both fluorimetric and electrochemical measurements.
- Subjects :
- UV-vis spectroscopy
Inorganic chemistry
chemistry.chemical_element
02 engineering and technology
Glassy carbon
010402 general chemistry
Electrochemistry
01 natural sciences
Fluorescence spectroscopy
hydrogen peroxide detection
Analytical Chemistry
lcsh:Biochemistry
chemistry.chemical_compound
Ultraviolet visible spectroscopy
lcsh:QD415-436
Physical and Theoretical Chemistry
photoactive material
Hydrogen peroxide
fluorimetry
Pt-porphyrin
021001 nanoscience & nanotechnology
Porphyrin
0104 chemical sciences
chemistry
electrochemistry
Electrode
0210 nano-technology
Platinum
Subjects
Details
- Language :
- English
- ISSN :
- 22279040
- Database :
- OpenAIRE
- Journal :
- Chemosensors
- Accession number :
- edsair.doi.dedup.....18ce4616cf150bf01c363bf612c3faca
- Full Text :
- https://doi.org/10.3390/chemosensors8020029