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Lower Bound on the Hartree-Fock Energy of the Electron Gas
- Source :
- Physical Review A, Physical Review A, 2019, 99, pp.052501. ⟨10.1103/PhysRevA.99.052501⟩, Physical Review A, American Physical Society 2019, 99, pp.052501. ⟨10.1103/PhysRevA.99.052501⟩
- Publication Year :
- 2019
- Publisher :
- HAL CCSD, 2019.
-
Abstract
- The Hartree-Fock ground state of the Homogeneous Electron Gas is never translation invariant, even at high densities. As proved by Overhauser, the (paramagnetic) free Fermi Gas is always unstable under the formation of spin or charge density waves. We give here the first explicit bound on the energy gain due to the breaking of translational symmetry. Our bound is exponentially small at high density, which justifies posteriori the use of the non-interacting Fermi Gas as a reference state in the large-density expansion of the correlation energy of the Homogeneous Electron Gas. We are also able to discuss the positive temperature phase diagram and prove that the Overhauser instability only occurs at temperatures which are exponentially small at high density. Our work sheds a new light on the Hartree-Fock phase diagram of the Homogeneous Electron Gas.<br />Extended version. Includes a new estimate on the critical temperature
- Subjects :
- Condensed Matter::Quantum Gases
Physics
Strongly Correlated Electrons (cond-mat.str-el)
[PHYS.MPHY]Physics [physics]/Mathematical Physics [math-ph]
Hartree–Fock method
FOS: Physical sciences
Mathematical Physics (math-ph)
01 natural sciences
Upper and lower bounds
010305 fluids & plasmas
Mathematics - Spectral Theory
Condensed Matter - Strongly Correlated Electrons
Homogeneous
0103 physical sciences
FOS: Mathematics
Atomic physics
[PHYS.COND.CM-SCE]Physics [physics]/Condensed Matter [cond-mat]/Strongly Correlated Electrons [cond-mat.str-el]
010306 general physics
Fermi gas
Spectral Theory (math.SP)
Astrophysics::Galaxy Astrophysics
Mathematical Physics
Phase diagram
[MATH.MATH-SP]Mathematics [math]/Spectral Theory [math.SP]
Subjects
Details
- Language :
- English
- ISSN :
- 24699926 and 24699934
- Database :
- OpenAIRE
- Journal :
- Physical Review A, Physical Review A, 2019, 99, pp.052501. ⟨10.1103/PhysRevA.99.052501⟩, Physical Review A, American Physical Society 2019, 99, pp.052501. ⟨10.1103/PhysRevA.99.052501⟩
- Accession number :
- edsair.doi.dedup.....1826aa83a441fca700f79ea2267f5256
- Full Text :
- https://doi.org/10.1103/PhysRevA.99.052501⟩