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Lower Bound on the Hartree-Fock Energy of the Electron Gas

Authors :
David Gontier
Mathieu Lewin
Christian Hainzl
CEntre de REcherches en MAthématiques de la DEcision (CEREMADE)
Université Paris Dauphine-PSL
Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)
Mathematisches Institut [Tübingen]
Eberhard Karls Universität Tübingen = Eberhard Karls University of Tuebingen
European Project: 725528,MDFT
Centre National de la Recherche Scientifique (CNRS)-Université Paris Dauphine-PSL
Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)
Source :
Physical Review A, Physical Review A, 2019, 99, pp.052501. ⟨10.1103/PhysRevA.99.052501⟩, Physical Review A, American Physical Society 2019, 99, pp.052501. ⟨10.1103/PhysRevA.99.052501⟩
Publication Year :
2019
Publisher :
HAL CCSD, 2019.

Abstract

The Hartree-Fock ground state of the Homogeneous Electron Gas is never translation invariant, even at high densities. As proved by Overhauser, the (paramagnetic) free Fermi Gas is always unstable under the formation of spin or charge density waves. We give here the first explicit bound on the energy gain due to the breaking of translational symmetry. Our bound is exponentially small at high density, which justifies posteriori the use of the non-interacting Fermi Gas as a reference state in the large-density expansion of the correlation energy of the Homogeneous Electron Gas. We are also able to discuss the positive temperature phase diagram and prove that the Overhauser instability only occurs at temperatures which are exponentially small at high density. Our work sheds a new light on the Hartree-Fock phase diagram of the Homogeneous Electron Gas.<br />Extended version. Includes a new estimate on the critical temperature

Details

Language :
English
ISSN :
24699926 and 24699934
Database :
OpenAIRE
Journal :
Physical Review A, Physical Review A, 2019, 99, pp.052501. ⟨10.1103/PhysRevA.99.052501⟩, Physical Review A, American Physical Society 2019, 99, pp.052501. ⟨10.1103/PhysRevA.99.052501⟩
Accession number :
edsair.doi.dedup.....1826aa83a441fca700f79ea2267f5256
Full Text :
https://doi.org/10.1103/PhysRevA.99.052501⟩