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Lock-in spin structures and ferrimagnetism in polar Ni 2−x Co x ScSbO 6 oxides

Authors :
Elena Solana-Madruga
J. Paul Attfield
Angel M. Arevalo-Lopez
Pascal Manuel
Anatoliy Senyshyn
Clemens Ritter
Kunlang Ji
School of Chemistry, University of Edinburgh
University of Edinburgh
Unité de Catalyse et Chimie du Solide - UMR 8181 (UCCS)
Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille
ISIS Facility
STFC Rutherford Appleton Laboratory (RAL)
Science and Technology Facilities Council (STFC)-Science and Technology Facilities Council (STFC)
Institut Laue-Langevin (ILL)
ILL
Structural Research
Technische Universität Darmstadt (TU Darmstadt)
Center for Science at Extreme Conditions
Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)
Technische Universität Darmstadt - Technical University of Darmstadt (TU Darmstadt)
Source :
Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2018, 54 (88), pp.12523-12526. ⟨10.1039/C8CC07556E⟩, Ji, K, Solana-madruga, E, Arevalo-lopez, A M, Manuel, P, Ritter, C, Senyshyn, A & Attfield, J P 2018, ' Lock-in spin structures and ferrimagnetism in polar Ni2−xCoxScSbO6 oxides ', Chemical Communications . https://doi.org/10.1039/C8CC07556E, 'Chemical Communications ', vol: 54, pages: 12523-12526 (2018), Chemical Communications, 2018, 54 (88), pp.12523-12526. ⟨10.1039/C8CC07556E⟩
Publication Year :
2018
Publisher :
HAL CCSD, 2018.

Abstract

International audience; The new phase Co2ScSbO6 and Ni2-xCoxScSbO6 solid solutions adopt the polar Ni3TeO6-type structure and order magnetically below 60 K. A series of long-period lock-in [0 0 1/3n] spin structures with n = 5, 6, 8 and 10 is discovered, coexisting with a ferrimagnetic [0 0 0] phase at high Co-contents. The presence of electrical polarisation and spontaneous magnetisations offers possibilities for multiferroic properties.

Details

Language :
English
ISSN :
13597345 and 1364548X
Database :
OpenAIRE
Journal :
Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2018, 54 (88), pp.12523-12526. ⟨10.1039/C8CC07556E⟩, Ji, K, Solana-madruga, E, Arevalo-lopez, A M, Manuel, P, Ritter, C, Senyshyn, A & Attfield, J P 2018, ' Lock-in spin structures and ferrimagnetism in polar Ni2−xCoxScSbO6 oxides ', Chemical Communications . https://doi.org/10.1039/C8CC07556E, 'Chemical Communications ', vol: 54, pages: 12523-12526 (2018), Chemical Communications, 2018, 54 (88), pp.12523-12526. ⟨10.1039/C8CC07556E⟩
Accession number :
edsair.doi.dedup.....175c87bd2807478e808c73c91f24cb23