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Nickel(II) complexes with Schiff-base ligands derived from epimeric pyranose backbones as 2,3-chelators: modeling the coordination chemistry of chitosan
- Source :
- Carbohydrate research. 343(7)
- Publication Year :
- 2007
-
Abstract
- Two mononuclear nickel(II) complexes with Schiff-base ligands derived from the epimeric sugars glucosamine and mannosamine have been synthesized. The X-ray crystal structure reveals a distorted octahedral geometry at the nickel(II) ions with an N4O2 donor set and the rare 2,3-chelation of the donor atoms of the carbohydrate backbone. Upon complexation only the glucopyranose ring maintains the 4C1 chair conformation, whereas the mannopyranose ring adopts the OS5 screw-boat conformation. Dimeric units of complex cations are formed by intermolecular hydrogen bonding which are further assembled by π-stacking affording one-dimensional chains with a twofold screw symmetry.
- Subjects :
- Models, Molecular
Stereochemistry
Cyclohexane conformation
Molecular Sequence Data
Molecular Conformation
chemistry.chemical_element
Ring (chemistry)
Crystallography, X-Ray
Ligands
Biochemistry
Analytical Chemistry
Coordination complex
chemistry.chemical_compound
Nickel
Octahedral molecular geometry
Electrochemistry
Organometallic Compounds
Schiff Bases
Chelating Agents
chemistry.chemical_classification
Chitosan
Schiff base
Molecular Structure
Hydrogen bond
Organic Chemistry
Hydrogen Bonding
General Medicine
Crystallography
chemistry
Pyranose
Carbohydrate Sequence
Subjects
Details
- ISSN :
- 00086215
- Volume :
- 343
- Issue :
- 7
- Database :
- OpenAIRE
- Journal :
- Carbohydrate research
- Accession number :
- edsair.doi.dedup.....1569c81a1e3e11d42ad486031f74bd57