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Palladium(0) catalyzed regioselective carbonyl propargylation across tetragonal tin(II) oxide via redox transmetallation

Authors :
Moloy Banerjee
Sujit Roy
Source :
Chemical communications (Cambridge, England). (4)
Publication Year :
2003

Abstract

Facile homopropargylation of aldehydes by propargyl bromides over tetragonal tin(II)oxide and catalytic palladium(0) occurs which is proposed to involve the prior formation of dinuclear allenylpalladium followed by redox transmetallation to beta-SnO.

Details

ISSN :
13597345
Issue :
4
Database :
OpenAIRE
Journal :
Chemical communications (Cambridge, England)
Accession number :
edsair.doi.dedup.....13871609544748cdcff8ab2795729c0e