PowerfulN-Monoalkylation of Linear Tetraamines via Bisaminal Intermediates

Authors :: Hélène Bernard
Nathalie Le Bris
Henri Handel
Géraldine Claudon
Chimie, Electrochimie Moléculaires et Chimie Analytique (CEMCA)
Institut Brestois Santé Agro Matière (IBSAM)
Université de Brest (UBO)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)
Source :: European Journal of Organic Chemistry, European Journal of Organic Chemistry, Wiley-VCH Verlag, 2004, 2004 (24), pp.5027-5030. ⟨10.1002/ejoc.200400459⟩
Publication Year :: 2004
Publisher :: HAL CCSD, 2004.
Abstract: The bisaminals obtained through the condensation of two linear tetraamines with glyoxal or pyruvic aldehyde were selectively alkylated with bromo- or α,ψ-dibromoalkanes in good yields at one of the secondary amino functions to give rise to N-monoalkylated tetraamines or linear octaamines. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

Language :: English
ISSN :: 1434193X and 10990690
Database :: OpenAIRE
Journal :: European Journal of Organic Chemistry, European Journal of Organic Chemistry, Wiley-VCH Verlag, 2004, 2004 (24), pp.5027-5030. ⟨10.1002/ejoc.200400459⟩
Accession number :: edsair.doi.dedup.....131c80f3d35dc4605bec13e758e6921d
Full Text :: https://doi.org/10.1002/ejoc.200400459⟩