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Cu-Catalyzed Oxidation of C2 and C3 Alkyl-Substituted Indole via Acyl Nitroso Reagents
- Source :
- Org Lett
- Publication Year :
- 2018
- Publisher :
- American Chemical Society (ACS), 2018.
-
Abstract
- The selective oxidation of C2-alkyl-substituted indoles to 3-oxindole and the selective C─H oxygenation or amination of C2,C3-dialkyl-substituted indoles at C2 are reported under mild conditions. The position of the alkyl substitution on the indole directs the reaction to different pathways under similar conditions.
- Subjects :
- Indoles
010402 general chemistry
01 natural sciences
Biochemistry
Medicinal chemistry
Catalysis
Article
chemistry.chemical_compound
Molecule
Physical and Theoretical Chemistry
Alkyl
Amination
Indole test
chemistry.chemical_classification
Molecular Structure
010405 organic chemistry
Chemistry
Organic Chemistry
Nitroso
Oxindoles
0104 chemical sciences
Reagent
Alkyl substitution
Oxidation-Reduction
Copper
Nitroso Compounds
Subjects
Details
- ISSN :
- 15237052 and 15237060
- Volume :
- 21
- Database :
- OpenAIRE
- Journal :
- Organic Letters
- Accession number :
- edsair.doi.dedup.....126796bd690bf372bdec872534c372a4