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Atom economical coupling of benzophenone and N-heterocyclic aromatics with SmI 2
- Source :
- Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2020, ⟨10.1039/D0CC05164K⟩, Chemical Communications, 2020, ⟨10.1039/D0CC05164K⟩
- Publication Year :
- 2020
- Publisher :
- HAL CCSD, 2020.
-
Abstract
- International audience; The use of stoechiometric SmI 2 in combination with benzophenone and N-heterocyclic aromatics such as bipyridine, phenanthroline and neat pyridine allows the direct ortho-coupling of both partners in an atom economical reaction free of any other coupling additives. The transformation was investigated by 1 H NMR, X-ray studies and theoretical calculations providing reaction intermediates and the reaction mechanism.
- Subjects :
- Reaction mechanism
010405 organic chemistry
Phenanthroline
Metals and Alloys
General Chemistry
Reaction intermediate
010402 general chemistry
01 natural sciences
Catalysis
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
Bipyridine
chemistry
Computational chemistry
Pyridine
Atom
Materials Chemistry
Ceramics and Composites
Proton NMR
Benzophenone
[CHIM]Chemical Sciences
Subjects
Details
- Language :
- English
- ISSN :
- 13597345 and 1364548X
- Database :
- OpenAIRE
- Journal :
- Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2020, ⟨10.1039/D0CC05164K⟩, Chemical Communications, 2020, ⟨10.1039/D0CC05164K⟩
- Accession number :
- edsair.doi.dedup.....11e9a5b2d4e147d5c5a2deaa9a9aebfa
- Full Text :
- https://doi.org/10.1039/D0CC05164K⟩