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Asymmetric Hydrogenation of α,β-Unsaturated Ester- Phosphonates
- Source :
- Advanced Synthesis and Catalysis, Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2009, 351 (9), pp.1423-1430. ⟨10.1002/adsc.200900051⟩
- Publication Year :
- 2009
- Publisher :
- HAL CCSD, 2009.
-
Abstract
- The rhodium-catalyzed asymmetric hydrogenation of readily available α,β-unsaturated esterphosphonates affords the corresponding α-chiral phosphonates in excellent yield and ee. The resulting products are useful multifunctional building blocks applied in the synthesis of physiologically active compounds.
- Subjects :
- 010405 organic chemistry
Chemistry
Asymmetric hydrogenation
Noyori asymmetric hydrogenation
chemistry.chemical_element
Homogeneous catalysis
General Chemistry
010402 general chemistry
01 natural sciences
0104 chemical sciences
3. Good health
Rhodium
Yield (chemistry)
Organic chemistry
[CHIM]Chemical Sciences
ComputingMilieux_MISCELLANEOUS
Subjects
Details
- Language :
- English
- ISSN :
- 16154150 and 16154169
- Database :
- OpenAIRE
- Journal :
- Advanced Synthesis and Catalysis, Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2009, 351 (9), pp.1423-1430. ⟨10.1002/adsc.200900051⟩
- Accession number :
- edsair.doi.dedup.....10c9aeeaf467f93c0adbd59e5ca8d5ff