Time-resolved UV-visible spectroelectrochemistry using transparent 3D-mesoporous nanocrystalline ITO electrodes

Efficient and rapid adsorption of microperoxidase 11 within a highly porous ITO thin film (200 nm) prepared by glancing angle deposition was achieved. Adsorbed redox molecules were reversibly and rapidly reduced throughout the 3D-conductive matrix in ca. 50 ms, allowing the heterogeneous electron transfer rate to be determined by derivative cyclic voltabsorptometry. © 2011 The Royal Society of Chemistry.