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Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals
- Source :
- Angewandte Chemie (International Ed. in English), Angewandte Chemie International Edition
- Publication Year :
- 2017
- Publisher :
- Wiley, 2017.
-
Abstract
- Black phosphorus intercalation compounds (BPICs) with alkali metals (namely: K and Na) have been synthesized in bulk by solid‐state as well as vapor‐phase reactions. By means of a combination of in situ X‐ray diffraction, Raman spectroscopy, and DFT calculations the structural behavior of the BPICs at different intercalation stages has been demonstrated for the first time. Our results provide a glimpse into the very first steps of a new family of intercalation compounds, with a distinct behavior as compared to its graphite analogues (GICs), showing a remarkable structural complexity and a dynamic behavior.
- Subjects :
- Diffraction
alkali metals
Inorganic chemistry
Intercalation (chemistry)
02 engineering and technology
DFT calculations
010402 general chemistry
01 natural sciences
Catalysis
Black phosphorus
symbols.namesake
Graphite
intercalation compounds
Chemistry
Communication
General Chemistry
General Medicine
Alkali metal
021001 nanoscience & nanotechnology
Communications
0104 chemical sciences
ddc:540
Black Phosphorus
Raman spectroscopy
symbols
Surface modification
0210 nano-technology
Subjects
Details
- ISSN :
- 00448249
- Volume :
- 129
- Database :
- OpenAIRE
- Journal :
- Angewandte Chemie
- Accession number :
- edsair.doi.dedup.....1058e6bae2d2d31c64bb6f8368673548