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Ring size-reactivity relationship in radical ring-opening copolymerisation of thionolactones with vinyl pivalate
- Source :
- Polymer Chemistry, Polymer Chemistry, 2022, 13 (45), pp.6284-6292. ⟨10.1039/d2py01153k⟩
- Publication Year :
- 2022
- Publisher :
- HAL CCSD, 2022.
-
Abstract
- International audience; The radical ring-opening copolymerisation of unsubstituted thionolactones of different ring sizes has been investigated. DFT calculations and experimental results show the importance of the stabilization of the intermediate ring-retained radical.
Details
- Language :
- English
- ISSN :
- 17599954 and 17599962
- Database :
- OpenAIRE
- Journal :
- Polymer Chemistry, Polymer Chemistry, 2022, 13 (45), pp.6284-6292. ⟨10.1039/d2py01153k⟩
- Accession number :
- edsair.doi.dedup.....0e5fa0c706126a04709088ee69f4e6a6