Back to Search
Start Over
Selective Aerobic Oxidation of Methylarenes to Benzaldehydes Catalyzed by N -Hydroxyphthalimide and Cobalt(II) Acetate in Hexafluoropropan-2-ol
- Source :
- Angewandte Chemie International Edition. 56:5912-5915
- Publication Year :
- 2017
- Publisher :
- Wiley, 2017.
-
Abstract
- Efficient and highly selective catalytic conditions for the aerobic autoxidation of methylarenes to benzaldehydes, based on N-hydroxyphthalimide (NHPI) and cobalt(II) acetate in 1,1,1,3,3,3-hexafluoropropan-2-ol (HFIP), were developed. The sustainable conditions enable a multigram scale preparation of benzaldehyde derivatives in high efficiency and with excellent chemoselectivity (up to 99 % conversion and 98 % selectivity).
- Subjects :
- Autoxidation
010405 organic chemistry
chemistry.chemical_element
General Medicine
General Chemistry
N-hydroxyphthalimide
010402 general chemistry
01 natural sciences
Catalysis
0104 chemical sciences
Benzaldehyde
chemistry.chemical_compound
chemistry
Organic chemistry
Cobalt(II) acetate
Chemoselectivity
Selectivity
Cobalt
Subjects
Details
- ISSN :
- 14337851
- Volume :
- 56
- Database :
- OpenAIRE
- Journal :
- Angewandte Chemie International Edition
- Accession number :
- edsair.doi.dedup.....0e007cd0d08a0ccb2e7595e83b506743