Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol

Authors :: Jens Beckmann
Jan Turek
Jiří Tydlitát
Aleš Růžička
Roman Jambor
Libor Dostál
Michal Aman
Chemistry
General Chemistry
Publication Year :: 2021
Publisher :: Royal Society of Chemistry, 2021.
Abstract: A stable ionic κ2Sn,P-coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri-substituted naphthalene ligand, which can act as either a reducing agent for a Ru(III) complex or as a κ2Sn,P-chelating ligand for Ru(II) compounds.

Subjects :: Ligand
Reducing agent
Metals and Alloys
Ionic bonding
General Chemistry
Medicinal chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
Benzylamine
chemistry
Benzyl alcohol
Materials Chemistry
Ceramics and Composites
Naphthalene

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