Back to Search
Start Over
Partially Reversible H 2 S Adsorption by MFM-300(Sc): Formation of Polysulfides
- Source :
- ACS Applied Materials & Interfaces, ACS Applied Materials & Interfaces, Washington, D.C. : American Chemical Society, 2020, 12 (16), pp.18885-18892. ⟨10.1021/acsami.0c02340⟩
- Publication Year :
- 2020
- Publisher :
- HAL CCSD, 2020.
-
Abstract
- The metal-organic framework (MOF)-type MFM-300(Sc) exhibits a combined physisorption and chemisorption capture of H2S, leading to a high uptake (16.55 mmol g-1) associated with high structural stability. The irreversible chemisorbed sulfur species were identified as low-order polysulfide (n = 2) species. The isostructural MFM-300(In) was demonstrated to promote the formation of different polysulfide species, paving the way toward a new methodology to incorporate polysulfides within MOFs for the generation of novel MOF-lithium/sulfur batteries.
- Subjects :
- Materials science
Hydrogen sulfide
Inorganic chemistry
chemistry.chemical_element
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Sulfur
0104 chemical sciences
chemistry.chemical_compound
Adsorption
Physisorption
chemistry
Chemisorption
[CHIM]Chemical Sciences
General Materials Science
Metal-organic framework
Isostructural
0210 nano-technology
Polysulfide
Subjects
Details
- Language :
- English
- ISSN :
- 19448244 and 19448252
- Database :
- OpenAIRE
- Journal :
- ACS Applied Materials & Interfaces, ACS Applied Materials & Interfaces, Washington, D.C. : American Chemical Society, 2020, 12 (16), pp.18885-18892. ⟨10.1021/acsami.0c02340⟩
- Accession number :
- edsair.doi.dedup.....0d36e4fa037c85f0feef97c49c732cf7