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Sugar and polyol solutions as effective solvent for biopolymers
- Source :
- Food Hydrocolloids 56 (2016), Food Hydrocolloids, 56, 144-149
- Publication Year :
- 2016
-
Abstract
- Ternary mixtures of biopolymers, sugars or polyols and water can be treated as a pseudo binary system with respect to melting of the biopolymer. Sugar and polyol solutions can be treated as an effective solvent, characterized by the density of hydroxyl groups available for intermolecular hydrogen bonding. Such a treatment has been shown earlier for the glass transitions of the ternary mixtures. Now we have analysed the melting behaviour of biopolymers in these ternary mixtures. If the melting points are plotted as function of the density of hydroxyl groups, all data for a variety of sugars and polyols collapse to a single curve. This master curve coincides with the prediction of the melting line for biopolymer/water mixtures as follows from Flory's theory. Such behaviour has been found for starch, gelatin, soy and sunflower proteins.
- Subjects :
- Hydrogen bonding
General Chemical Engineering
02 engineering and technology
engineering.material
State diagram
0404 agricultural biotechnology
Polyol
Organic chemistry
Binary system
VLAG
chemistry.chemical_classification
Chemistry
Hydrogen bond
Intermolecular force
04 agricultural and veterinary sciences
General Chemistry
021001 nanoscience & nanotechnology
040401 food science
Solvent
Reformulation
Melting point
engineering
Food Technology
Biopolymer
Biopolymer melting
0210 nano-technology
Ternary operation
Food Science
Subjects
Details
- Language :
- English
- ISSN :
- 0268005X
- Database :
- OpenAIRE
- Journal :
- Food Hydrocolloids 56 (2016), Food Hydrocolloids, 56, 144-149
- Accession number :
- edsair.doi.dedup.....0b3c9b757614cf584e16149907cfff0b