Cobalt and Iron Ions in MgO Nanocrystals: Should They Stay or Should They Go

Identification and manipulation of transition-metal ion impurities in oxide nanoparticles require an in-depth understanding of their stability, segregation behavior, and, at the same time, knowledge about their surface reactivity. Powders of magnesium oxide nanoparticles with admixtures of iron or cobalt ions, as two next neighbors in the periodic table, were synthesized in the gas phase via injection of metal–organic precursors into the magnesium combustion flame followed by temperature quenching of resulting nanocrystals in argon. In these model systems of cubic nanocrystals, we explored the distinct stability of these impurities in great detail. While Co2+ ions keep their divalent valence state and substitute the host ions in the cationic sublattice, Fe3+ ions emerge due to the energy gain provided by charge compensation and impurity–vacancy complex formation. The very different behavior of Co and Fe ions in the MgO host lattice, their changes in the local environment, and the different trends in segre...