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Design and Synthesis of Ir/Ru Pyrochlore Catalysts for the Oxygen Evolution Reaction Based on Their Bulk Thermodynamic Properties

Authors :
Daniel F. Abbott
Petr Krtil
Rebecca K. Pittkowski
Ivano E. Castelli
Roman Nebel
Emiliana Fabbri
Elena Marelli
Thomas J. Schmidt
Kateřina Macounová
Source :
Abbott, D F, Pittkowski, R K, Macounová, K, Nebel, R, Marelli, E, Fabbri, E, Castelli, I E, Krtil, P & Schmidt, T J 2019, ' Design and Synthesis of Ir/Ru Pyrochlore Catalysts for the Oxygen Evolution Reaction Based on Their Bulk Thermodynamic Properties ', ACS Applied Materials and Interfaces, vol. 11, no. 41, pp. 37748-37760 . https://doi.org/10.1021/acsami.9b13220, ACS Applied Materials & Interfaces
Publication Year :
2019

Abstract

Density Functional Theory (DFT) has proven to be an invaluable and effective tool for identifying highly active electrocatalysts for the oxygen evolution reaction (OER). Herein we take a computational approach in order to first identify a series of rare-earth pyrochlore oxides based on Ir and Ru as potential OER catalysts. The DFT-based phase diagrams, Pourbaix diagrams (E vs. pH), projected density of states (PDOS), and band energy diagrams were used to identify prospective OER catalysts based on rare earth Ir and Ru pyrochlores. The predicted materials were synthesized using the spray-freeze freeze-drying approach to afford nanoparticulate oxides conforming to the pyrochlore structural type A2B2O7 where A = Nd, Gd, or Yb and B = Ir or Ru. In agreement with the computed Pourbaix diagrams, the materials were found to be moderately stable under OER conditions. All prepared materials show higher stability as compared to the benchmark IrO2 catalyst and the OER mass activity of Yb2Ir2O7 and the ruthenate pyrochlores (Nd2Ru2O7, Gd2Ru2O7, and Yb2Ru2O7) were also found to exceed that of the benchmark IrO2 catalyst. We find that the OER activity of each pyrochlore series (i.e. iridate or ruthenate) generally improves as the size of the A-site cation decreases, indicating that maintaining control over the local structure can be used to influence the electrocatalytic properties.

Details

Language :
English
Database :
OpenAIRE
Journal :
Abbott, D F, Pittkowski, R K, Macounová, K, Nebel, R, Marelli, E, Fabbri, E, Castelli, I E, Krtil, P & Schmidt, T J 2019, ' Design and Synthesis of Ir/Ru Pyrochlore Catalysts for the Oxygen Evolution Reaction Based on Their Bulk Thermodynamic Properties ', ACS Applied Materials and Interfaces, vol. 11, no. 41, pp. 37748-37760 . https://doi.org/10.1021/acsami.9b13220, ACS Applied Materials & Interfaces
Accession number :
edsair.doi.dedup.....0af58b5630569c37f7a37eb8b5f8c54a