Developmental Study of Soot-Oxidation Catalysts for Fireplaces: The Effect of Binder and Preparation Techniques on Catalyst Texture and Activity

An awareness of increasing climate and health problems has driven the development of new functional and affordable soot-oxidation catalysts for stationary sources, such as fireplaces. In this study, Al(OH)3, water glass and acidic aluminium phosphate binder materials were mixed with soot-oxidation catalysts. The effect of the binder on the performance of the Ag/La-Al2O3 catalyst was examined, while the Pt/La-Al2O3 catalyst bound with Al(OH)3 was used as a reference. Soot was oxidised above 340 &deg
C on the Ag/La-Al2O3 catalyst, but at 310 &deg
C with same catalyst bound with Al(OH)3. The addition of water glass decreased the catalytic performance because large silver crystals and agglomeration resulted in a blockage of the support material&rsquo
s pores. Pt/La-Al2O3 bound with Al(OH)3 was ineffective in a fireplace environment. We believe that AgOx is the active form of silver in the catalyst. Hence, Ag/La-Al2O3 was shown to be compatible with the Al(OH)3 binder as an effective catalyst for fireplace soot oxidation.