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Phosphorylated-calix[4]arene double-deckers of single rare earth metal ions

Authors :
Scott J. Dalgarno
Paul Kögerler
Euan K. Brechin
Jan van Leusen
Marjan Hosseinzadeh
Natalya V. Izarova
Sergio Sanz
Source :
Hosseinzadeh, M, Sanz, S, Van Leusen, J, Izarova, N V, Brechin, E K, Dalgarno, S & Kögerler, P 2021, ' Phosphorylated-calix[4]arene double-deckers of single rare earth metal ions ', Chemical Communications . https://doi.org/10.1039/D1CC02910J, Chemical communications 57(65), 8087-8090 (2021). doi:10.1039/D1CC02910J
Publication Year :
2021

Abstract

Combination of phosphoryl and calix[4]arene moieties in the same organic framework (LPO) directs the formation of homoleptic double-decker complexes [LnIII(LPO)2](O3SCF3)3 for Ln = Tb and Dy, with the latter displaying slow relaxation of the magnetisation.

Details

ISSN :
1364548X
Volume :
57
Issue :
65
Database :
OpenAIRE
Journal :
Chemical communications (Cambridge, England)
Accession number :
edsair.doi.dedup.....0a1c1664e9ac3ca29f2c72cb1072a4c7