A Convenient Preparation of 3-Substituted Furans: Synthesis of Perillene and Dendrolasin

Authors :: Rachid Baati
D. K. Barma
John R. Falck
Charles Mioskowski
Abhijit Kundu
Source :: Organic Letters. 4:1387-1389
Publication Year :: 2002
Publisher :: American Chemical Society (ACS), 2002.
Abstract: A variety of 3-substituted furans, including the natural products perillene and dendrolasin, are obtained in good yield via reductive annulation of 1,1,1-trichloroethyl propargyl ethers using catalytic Cr(II) regenerated by Mn/TMSCl. [reaction: see text]

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