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Crystal structure of 3,6-dihy­droxy-4,5-di­methyl­benzene-1,2-dicarbaldehyde

Authors :
Shiomi Yagi
Kazuki Nishiyama
Shu Yamazaki
Tomoyuki Haraguchi
Takashiro Akitsu
Source :
Acta Crystallographica Section E: Crystallographic Communications, Acta Crystallographica Section E: Crystallographic Communications, Vol 74, Iss 10, Pp 1424-1426 (2018)
Publication Year :
2018
Publisher :
International Union of Crystallography, 2018.

Abstract

The planar achiral title compound has C 2v symmetry and crystallizes in the chiral space group P21.<br />The title compound, C10H10O4, was synthesized from tetra­methyl-1,4-benzo­quinone. In the crystal, the almost planar mol­ecule (r.m.s. deviation = 0.024 Å) forms intra­molecular hydrogen bonds between the aldehyde and hy­droxy groups and exhibits C 2v symmetry. This achiral mol­ecule crystallizes in the chiral space group P21 with inter­molecular O—H⋯O and C—H⋯O hydrogen bonding and C—H⋯π and C=O⋯π inter­actions stabilizing the crystal packing.

Details

Language :
English
ISSN :
20569890
Volume :
74
Issue :
Pt 10
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E: Crystallographic Communications
Accession number :
edsair.doi.dedup.....0993378bfcfee04d0601168f6b8dc232