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Aryne triggered [2,3]-sigmatropic rearrangement of allyl and propargyl thioethers
- Source :
- Organic & Biomolecular Chemistry. 15:4946-4950
- Publication Year :
- 2017
- Publisher :
- Royal Society of Chemistry (RSC), 2017.
-
Abstract
- An efficient protocol for [2,3]-sigmatropic rearrangement of allyl and propargyl thioethers is reported. The key sulfonium ylide intermediate is in situ formed via S-arylation of arynes. This transition metal-free method allows for ready access to a wide array of functionalized thioether derivatives in good to excellent yields.
- Subjects :
- chemistry.chemical_classification
010405 organic chemistry
Sulfonium
Stereochemistry
2,3-sigmatropic rearrangement
Organic Chemistry
010402 general chemistry
01 natural sciences
Biochemistry
Medicinal chemistry
Aryne
0104 chemical sciences
chemistry.chemical_compound
Thioether
chemistry
Ylide
Propargyl
Physical and Theoretical Chemistry
Subjects
Details
- ISSN :
- 14770539 and 14770520
- Volume :
- 15
- Database :
- OpenAIRE
- Journal :
- Organic & Biomolecular Chemistry
- Accession number :
- edsair.doi.dedup.....072b8cd464ed627457a866cce9b64e72