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Hydrothermal deposition as a novel method for the preparation of Co–Mn mixed oxide catalysts supported on stainless steel meshes: application to VOC oxidation
- Source :
- Environmental Science and Pollution Research. 29:5172-5183
- Publication Year :
- 2021
- Publisher :
- Springer Science and Business Media LLC, 2021.
-
Abstract
- The aim of this work was to develop a novel method for the preparation of structured Co-Mn mixed oxide catalysts: deposition on stainless steel meshes by hydrothermal synthesis. The use of meshes enabled the deposition of a thin layer of the active phase, which significantly suppressed the influence of internal diffusion. Consequently, the prepared catalysts exhibited from 48 to 114 times higher catalytic activity in ethanol oxidation than the commercial pelleted Co-Mn-Al catalyst. Moreover, we have shown that their catalytic activity correlated with the amount of surface oxygen vacancies determined by XPS. Finally, the outstanding activity of the catalyst with Co:Mn ratio of 0.5 was ascribed to the mutual effect of high number of oxygen vacancies and exceptional redox properties.
- Subjects :
- Volatile Organic Compounds
Ethanol
Materials science
Health, Toxicology and Mutagenesis
chemistry.chemical_element
Oxides
General Medicine
Stainless Steel
Pollution
Redox
Oxygen
Catalysis
chemistry.chemical_compound
chemistry
X-ray photoelectron spectroscopy
Chemical engineering
Environmental Chemistry
Hydrothermal synthesis
Mixed oxide
Deposition (phase transition)
Oxidation-Reduction
Subjects
Details
- ISSN :
- 16147499 and 09441344
- Volume :
- 29
- Database :
- OpenAIRE
- Journal :
- Environmental Science and Pollution Research
- Accession number :
- edsair.doi.dedup.....052968215dfa5a9b69f8ada0762e65dc