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Activations of all Bonds to Silicon (Si-H, Si-C) in a Silane with Extrusion of [CoSiCo] Silicide Cores
- Source :
- Journal of the American Chemical Society. 141(22)
- Publication Year :
- 2019
-
Abstract
- The [BP3iPr]Co(I) synthon Na(THF)6{[BP3iPr]CoI} (1, [BP3iPr] = κ3-PhB(CH2PiPr2)3–) reacts with PhSiH3 or SiH4 to form unusual {[BP2iPr](SiH2R)CoH2}═Si═{H2Co[BP3iPr]} species (R = Ph, 2a; R = H, 2b;...
- Subjects :
- Models, Molecular
Silicon
Chemistry
Extramural
Synthon
Molecular Conformation
chemistry.chemical_element
General Chemistry
Cobalt
Silanes
010402 general chemistry
01 natural sciences
Biochemistry
Silane
Catalysis
Molecular conformation
0104 chemical sciences
3. Good health
chemistry.chemical_compound
Crystallography
Colloid and Surface Chemistry
Silicide
Extrusion
Subjects
Details
- ISSN :
- 15205126
- Volume :
- 141
- Issue :
- 22
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....047960d484dc380e41d51522b24bb81c