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Intensification of volatile organic compound absorption in a compact wet scrubber at co-current flow

Authors :
Christophe Renner
Annabelle Couvert
Pierre-François Biard
Institut des Sciences Chimiques de Rennes (ISCR)
Université de Rennes 1 (UR1)
Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes)
Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Water Research Center
Veolia Environnement Research and Innovation
The authors are grateful to the French National Agency of the Technological Research (Agence Nationale de la Recherche Technologique, ANRT) for the CIFRE grant N° 511/2006.
ANR-05-JCJC-0147,SG-Phmètre,Microsystème de mesure de charges en solution et de pH en technologie Transistor Film Mince à grille suspendue(2005)
Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes)
Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Source :
Chemosphere, Chemosphere, Elsevier, 2017, 173, pp.612-621. ⟨10.1016/j.chemosphere.2017.01.075⟩, Chemosphere, 2017, 173, pp.612-621. ⟨10.1016/j.chemosphere.2017.01.075⟩
Publication Year :
2016

Abstract

International audience; Three volatile organic compounds (VOC) with no acidic or basic function (butanol, butyraldehyde, methylethylketone), encountered at low concentrations in odorous effluents, were absorbed in water in a compact wet scrubber. This gas-liquid contactor consisted of a wire mesh packing structure where the gas phase flows at high velocity (>12 m s(-1)). A very turbulent two-phase downward flow could be observed in the scrubber with dispersed fine droplets (around 10 μm). For compounds showing a good affinity for water, such as butanol, removal efficiencies up to 90% were measured for a short contactor length of 32 cm leading to a gas residence time of 20 ms. However, the removal efficiency of butyraldehyde, which is poorly soluble in water, ranged between 10 and 30%. Mass-transfer modeling was achieved and underlined that working with several small scrubbers in series, fed with an unloaded solution, is effective to improve the removal efficiency. The influences of the VOC/solvent affinity, the contactor length, and the mass-transfer and hydrodynamic parameters on the removal efficiency were evaluated through a sensitivity analysis.

Details

ISSN :
18791298 and 00456535
Volume :
173
Database :
OpenAIRE
Journal :
Chemosphere
Accession number :
edsair.doi.dedup.....041e46518e0ee823174bc3450aeea68e