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PHOTOCATALYTIC OXIDATION OF A HAZARDOUS PHENOLIC COMPOUND OVER TiO2 IN A BATCH SYSTEM

Authors :
Yassine Kadmi
Ecaterina Matei
Lidia Favier
Cristina-Gabriela Grigoras
Andrei Ionut Simion
Abdelkrim Bouzaza
Institut des Sciences Chimiques de Rennes (ISCR)
Université de Rennes 1 (UR1)
Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes)
Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
University of Bacău Vasile Alecsandri
Jonchère, Laurent
Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes)
Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Source :
Environmental Engineering and Management Journal, Environmental Engineering and Management Journal, "Gheorghe Asachi" Technical University of Iaşi, 2016, 15 (5), pp.1059--1067, Environmental Engineering and Management Journal, 2016, 15 (5), pp.1059--1067, HAL
Publication Year :
2016
Publisher :
HAL CCSD, 2016.

Abstract

International audience; Recently, environmental scientists have been focused their attention on the occurrence and the elimination of specific organic compounds in water. Among them, chlorophenols are considered to be a public health problem due to their carcinogenic properties. Thus, there is an important need to find new strategies to efficiently transform these compounds to no toxic or inactive by-products. In this work the photocatalytic removal of 2,4-dichlorophenol in water solution was investigated at laboratory scale in a batch photoreactor using a commercial titanium dioxide as catalyst. Effects of different operating parameters such as initial pollutant concentration, catalyst load and UV-light intensities on the photocatalytic elimination efficiency were evaluated in detail for future practical application purposes. Obtained data clearly showed an optimum degradation of the target compound under an initial pollutant concentration of 1.5 mg/L, a titanium dioxide concentration of 1 g/L and for UV-light intensity of 59.6 W/m(2). The total organic carbon removal was also calculated in order to confirm the mineralization of 2,4-dichlorophenol. The obtained data showed a higher mineralization yield under the optimized photocatalytic reaction conditions demonstrating the performance of the photocatalytic oxidation to remove the target molecule at low concentrations from aqueous medium.

Details

Language :
English
ISSN :
15829596 and 18433707
Database :
OpenAIRE
Journal :
Environmental Engineering and Management Journal, Environmental Engineering and Management Journal, "Gheorghe Asachi" Technical University of Iaşi, 2016, 15 (5), pp.1059--1067, Environmental Engineering and Management Journal, 2016, 15 (5), pp.1059--1067, HAL
Accession number :
edsair.doi.dedup.....038c39d5bd1611ba6a632c1db1dd6341