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Unconventional Biradical Character of Titanium Enolates
- Source :
- Journal of the American Chemical Society. 130:3242-3243
- Publication Year :
- 2008
- Publisher :
- American Chemical Society (ACS), 2008.
-
Abstract
- Experimental and theoretical studies evidence an unconventional biradical character for the titanium enolates derived from α-alkoxy ketones and TiCl4. EPR experiments and ab initio calculations suggest that these titanium enolates have an open shell electronic ground state.
Details
- ISSN :
- 15205126 and 00027863
- Volume :
- 130
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....0376a28670edba217e521b5faffbb6f2