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New high temperature dielectrics: Bi-free tungsten bronze ceramics with stable permittivity over a very wide temperature range
- Source :
- Brown, T, Brown, A P, Hall, D A, Hooper, T E, Li, Y, Micklethwaite, S, Aslam, Z & Milne, S J 2020, ' New High Temperature Dielectrics: Bi-free tungsten bronze ceramics with stable permittivity over a very wide temperature range ', Journal of the European Ceramic Society . https://doi.org/10.1016/j.jeurceramsoc.2020.10.034
- Publication Year :
- 2021
- Publisher :
- Elsevier BV, 2021.
-
Abstract
- High relative permittivity, er, over a very wide temperature range, −65 °C to 325 °C, is presented for ceramics designed to be compatible with base metal electrode multilayer capacitor manufacturing processes. We report a ≥ 300 °C potential Class II capacitor material, free from Bi or Pb ions, developed by doping Sr2NaNb5O15 with Ca2+, Y3+ and Zr4+ ions, according to the formulation Sr2−2zCazYzNaNb5-zZrzO15. For sample composition z = 0.025, er values are 1565 ± 15 % (1 kHz) from −65 °C to 325 °C. At a slightly higher level of doping, z = 0.05, er values are 1310 ± 10 % from −65 °C to 300 °C. Values of the dielectric loss tangent, tanδ are ≤ 0.025 from −60 °C to 290 °C, for z = 0.025, with tanδ increasing to 0.035 at 325 °C. Microstructural analyses exclude core-shell mechanisms being responsible for the flattening of the er –T response.
- Subjects :
- 010302 applied physics
Permittivity
Materials science
Doping
Analytical chemistry
Relative permittivity
chemistry.chemical_element
02 engineering and technology
Dielectric
Atmospheric temperature range
Tungsten
021001 nanoscience & nanotechnology
01 natural sciences
chemistry
visual_art
0103 physical sciences
Materials Chemistry
Ceramics and Composites
visual_art.visual_art_medium
Dielectric loss
Ceramic
0210 nano-technology
Subjects
Details
- ISSN :
- 09552219
- Volume :
- 41
- Database :
- OpenAIRE
- Journal :
- Journal of the European Ceramic Society
- Accession number :
- edsair.doi.dedup.....029dcceccd6693179ee5588e6a428ac3