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Influence of derivatization on the chiral selectivity of cyclodextrins: Alkylated/acylated cyclodextrins and γ-/δ-lactones as an example
- Source :
- Journal of Microcolumn Separations. 3:395-402
- Publication Year :
- 1991
- Publisher :
- Wiley, 1991.
-
Abstract
- Selectively alkylated and acylated cyclodextrin derivatives are suitable stationary phases for capillary GC. To obtain a closer insight into the separation mechanism, an inverse substituted cyclodextrin derivative was synthesized and characterized, and its chiral selectivity was compared with a traditionally substituted and characterized cyclodextrin. The influence of a polar group in the cyclodextrin molecule on the enantioselectivity for γ-/δ-lactones is shown with a new, diacylated, cyclodextrin derivative.
Details
- ISSN :
- 1520667X and 10407685
- Volume :
- 3
- Database :
- OpenAIRE
- Journal :
- Journal of Microcolumn Separations
- Accession number :
- edsair.doi.dedup.....02480e3c4ebfb8ce43a60f61365cfb42
- Full Text :
- https://doi.org/10.1002/mcs.1220030503