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Self-Assembly of TbPc 2 Single-Molecule Magnets on Surface through Multiple Hydrogen Bonding

Authors :
Federico Bertani
Matteo Mannini
Antonino E. Giuffrida
Alessandro Pedrini
Lorenzo Poggini
Guglielmo G. Condorelli
Irene Cimatti
Edwige Otero
Philippe Sainctavit
Michele Suman
Philippe Ohresser
Martina Torelli
Cristina Tudisco
Enrico Dalcanale
Department of Chemistry 'Ugo Schiff'
Università degli Studi di Firenze = University of Florence [Firenze] (UNIFI)
Synchrotron SOLEIL (SSOLEIL)
Centre National de la Recherche Scientifique (CNRS)
Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC)
Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de recherche pour le développement [IRD] : UR206-Muséum national d'Histoire naturelle (MNHN)-Centre National de la Recherche Scientifique (CNRS)
Department of Organic and Industrial Chemistry
University of Parma = Università degli studi di Parma [Parme, Italie]
Università degli Studi di Firenze = University of Florence (UniFI)
Muséum national d'Histoire naturelle (MNHN)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de recherche pour le développement [IRD] : UR206-Centre National de la Recherche Scientifique (CNRS)
Università degli studi di Parma = University of Parma (UNIPR)
Source :
Small, Small, Wiley-VCH Verlag, 2018, 14 (5), pp.1702572. ⟨10.1002/smll.201702572⟩, Small, 2018, 14 (5), pp.1702572. ⟨10.1002/smll.201702572⟩
Publication Year :
2018
Publisher :
HAL CCSD, 2018.

Abstract

The complexation between 2-ureido-4[1H]-pyrimidinone (UPy) and 2,7-diamido-1,8-naphthyridine (NaPy) is used to promote the mild chemisorption of a UPy-functionalized terbium(III) double decker system on a silicon surface. The adopted strategy allows the single-molecule magnet behavior of the system to be maintained unaltered on the surface.

Details

Language :
English
ISSN :
16136810 and 16136829
Database :
OpenAIRE
Journal :
Small, Small, Wiley-VCH Verlag, 2018, 14 (5), pp.1702572. ⟨10.1002/smll.201702572⟩, Small, 2018, 14 (5), pp.1702572. ⟨10.1002/smll.201702572⟩
Accession number :
edsair.doi.dedup.....023ff4477a76f5c6b4a51d2f36b5fa7d
Full Text :
https://doi.org/10.1002/smll.201702572⟩