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Solvothermal Synthesis of a Novel Calcium Metal-Organic Framework: High Temperature and Electrochemical Behaviour
- Source :
- Molecules, Vol 26, Iss 7048, p 7048 (2021), Molecules; Volume 26; Issue 22; Pages: 7048, Molecules
- Publication Year :
- 2021
- Publisher :
- MDPI AG, 2021.
-
Abstract
- The rapid growth in the field of metal-organic frameworks (MOFs) over recent years has highlighted their high potential in a variety of applications. For biological and environmental applications MOFs with low toxicity are vitally important to avoid any harmful effects. For this reason, Ca-based MOFs are highly desirable owing to their low cost and high biocompatibility. Useful Ca MOFs are still rare owing to the ionic character and large size of the Ca2+ ion tending to produce dense phases. Presented here is a novel Ca-based MOF containing 2,3-dihyrdoxyterephthalate (2,3-dhtp) linkers Ca(2,3-dhtp)(H2O) (SIMOF-4). The material undergoes a phase transformation on heating, which can be followed by variable temperature powder X-ray diffraction. The structure of the high temperature form was obtained using single-crystal X-ray diffraction. The electrochemical properties of SIMOF-4 were also investigated for use in a Na ion battery.
- Subjects :
- Battery (electricity)
Materials science
Biocompatibility
Solvothermal synthesis
Pharmaceutical Science
Ionic bonding
Organic chemistry
02 engineering and technology
010402 general chemistry
Electrochemistry
MOF
calcium MOF
electrochemistry
scXRD
VTXRD
bioMOF
01 natural sciences
Article
Analytical Chemistry
Ion
QD241-441
Phase (matter)
Drug Discovery
Physical and Theoretical Chemistry
021001 nanoscience & nanotechnology
0104 chemical sciences
Chemical engineering
Chemistry (miscellaneous)
Molecular Medicine
Metal-organic framework
0210 nano-technology
Subjects
Details
- Language :
- English
- ISSN :
- 14203049
- Volume :
- 26
- Issue :
- 7048
- Database :
- OpenAIRE
- Journal :
- Molecules
- Accession number :
- edsair.doi.dedup.....01668f5db5a0ab304ebe7f9732ab00fc