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A Neutral Naphthalene Diimide [2]Rotaxane

Authors :
J. Fraser Stoddart
Marco Frasconi
Carson J. Bruns
Julien Iehl
Henri Pierre Jacquot De Rouville
Amy A. Sarjeant
Psaras L. McGrier
Source :
Organic Letters. 14:5188-5191
Publication Year :
2012
Publisher :
American Chemical Society (ACS), 2012.

Abstract

A neutral donor-acceptor [2]rotaxane, which has been synthesized using click chemistry, has had its solid-state structure and superstructure elucidated by X-ray crystallography. Both dynamic (1)H NMR spectroscopy and electrochemical investigations have been employed in an attempt to shed light on both geometrical reorganization and redox-switching processes that are occurring or can be induced within the [2]rotaxane.

Details

ISSN :
15237052 and 15237060
Volume :
14
Database :
OpenAIRE
Journal :
Organic Letters
Accession number :
edsair.doi.dedup.....008293448b9371e8f11f1bee94c6e63b
Full Text :
https://doi.org/10.1021/ol3022963