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Combination of phosphonium and ammonium pendant groups in cationic conjugated polyelectrolytes based on regioregular poly(3-hexylthiophene) polymer chains
- Source :
- European Polymer Journal. 100:200-208
- Publication Year :
- 2018
- Publisher :
- Elsevier BV, 2018.
-
Abstract
- A series of novel polythiophene-based cationic conjugated polyelectrolytes with phosphonium and ammonium pendants were prepared by modifying regioregular poly[3-(6-bromohexyl)thiophene] using a simple quaternization reaction with appropriate phosphine or amine. Partial transformation of the bromide end-groups of the polymer precursor with amine allowed adding the phosphine agent, thereby enabling quantitative transformation into a novel conjugated polyelectrolyte with phosphonium and ammonium groups in the same polymer main-chains. The properties of the synthesized polyelectrolytes in solution (water, methanol, DMSO and chloroform) were analyzed by UV/vis, luminescence, NMR, light scattering and TGA measurements. To test the prepared polyelectrolytes as potential luminescence sensors, fluorescence quenching measurements were performed in water, using K4[Fe(CN)6] and K3[Fe(CN)6] as quenchers. This study showed that polyelectrolytes containing both types of ionic pendant groups (phosphonium and ammonium) are more efficiently quenched.
- Subjects :
- Polymers and Plastics
Organic Chemistry
Cationic polymerization
General Physics and Astronomy
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Conjugated Polyelectrolytes
Polyelectrolyte
0104 chemical sciences
chemistry.chemical_compound
chemistry
Bromide
Polymer chemistry
Materials Chemistry
Thiophene
Polythiophene
Phosphonium
0210 nano-technology
Phosphine
Subjects
Details
- ISSN :
- 00143057
- Volume :
- 100
- Database :
- OpenAIRE
- Journal :
- European Polymer Journal
- Accession number :
- edsair.doi...........ff0d81d48a20af45ea1b2eaa53aec00f