Electrophilic cleavage of carbon-fluorine bonds in hydrido trifluoromethyl complexes of platinum(II) by proton acids. Synthesis of hydrido carbene and hydrido carbonyl derivatives and x-ray structures of trans-PtH(CF3)(PPh3)2 (180 K) and trans-[PtH[cyclic](COCH2CH2O)(PPh3)2]BF4 (298 K)

Authors :: Gabriella Bombieri
Franco Benetollo
Rino A. Michelin
Gervais Chapuis
Giuseppe Guadalupi
Renzo Ros
Source :: Inorganic Chemistry. 28:840-846
Publication Year :: 1989
Publisher :: American Chemical Society (ACS), 1989.

Subjects :: Tetrafluoroborate
Trifluoromethyl
Stereochemistry
chemistry.chemical_element
Tricyclohexylphosphine
Inorganic Chemistry
chemistry.chemical_compound
chemistry
Electrophile
Molecule
Physical and Theoretical Chemistry
Triphenylphosphine
Platinum
Carbene

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