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Al2O3-modified CuO-CeO2 catalyst for simultaneous removal of NO and toluene at wide temperature range
- Source :
- Chemical Engineering Journal. 397:125419
- Publication Year :
- 2020
- Publisher :
- Elsevier BV, 2020.
-
Abstract
- A series of Al2O3-modified CuO-CeO2 (CuCeAlx) was synthesized to reveal the effect of Al2O3 addition on catalytic performance and the proposed mechanism for simultaneous removal of NO and toluene at a broad temperature range. BET, XRD, TEM, XPS, NH3-TPD, H2-TPR, and in situ DRIFTS were used to characterize these catalysts. Results demonstrated that Al2O3-modified CuO-CeO2 catalysts showed the excellent NH3-SCR performance at a broad temperature range (200–400 °C) and good low-temperature activity for toluene oxidation. The modification of Al2O3 significantly tunes the physical and textural properties and induces the formation of oxygen vacancies via the interaction between Ce4+/Ce3+ and Cu2+/Cu+ (Ce4+ + Cu+ ↔ Ce3+ + Cu2+). Besides, the inhibition effect of NH3 on toluene oxidation was confirmed in that the active oxygen species reacted preferentially with NH3 rather than the oxidation intermediates of toluene, while NO had a promotional effect on toluene oxidation owing to the reaction of C7H8 + 18NO = 9 N2 + 7CO2 + 4H2O. At the same time, toluene could also be reducing agents of NO, which was beneficial to NH3-SCR reaction, Based on the results, the proposed mechanism for simultaneous removal of toluene and NO over Al2O3-modified CuO-CeO2 catalysts was revealed.
- Subjects :
- In situ
Chemistry
Reducing agent
General Chemical Engineering
Inorganic chemistry
chemistry.chemical_element
02 engineering and technology
General Chemistry
Atmospheric temperature range
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Toluene
Oxygen
Industrial and Manufacturing Engineering
Toluene oxidation
0104 chemical sciences
Catalysis
chemistry.chemical_compound
X-ray photoelectron spectroscopy
Environmental Chemistry
0210 nano-technology
Subjects
Details
- ISSN :
- 13858947
- Volume :
- 397
- Database :
- OpenAIRE
- Journal :
- Chemical Engineering Journal
- Accession number :
- edsair.doi...........fda751c7d8a0f1f56c8fb6942e6f898e