The sandwich dimeric form of a CsIcomplex of 18-crown-6 with bridging iodide ions

Authors :: Tae Ho Kim
Ki-Min Park
Jineun Kim
Shim Sung Lee
Jae Sang Kim
Source :: Acta Crystallographica Section E Structure Reports Online. 57:m357-m358
Publication Year :: 2001
Publisher :: International Union of Crystallography (IUCr), 2001.
Abstract: The sandwich dimeric structure of di-μ-iodo-bis[(1,4,7,10,13,16-hexaoxacyclooctadecane)caesium(I)] p-xylene solvate, [Cs2I2(C12H24O6)2]·C8H10, has been characterized by X-ray crystallography. The complex adopts an encapsulate of a molecular dimeric array [Cs(18-crown-6)(μ-I)]2·C8H10. Two Cs(18-crown-6)+ moieties are doubly linked by two iodide ions. The molecule has crystallographic 2/m (C2h) symmetry.

Subjects :: chemistry.chemical_classification
Crystallography
chemistry.chemical_compound
Bridging (networking)
Chemistry
Iodide
18-Crown-6
General Materials Science
General Chemistry
Condensed Matter Physics
Ion

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