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One-pot cascade transformation of xylose into γ-valerolactone (GVL) over bifunctional Brønsted–Lewis Zr–Al-beta zeolite

Authors :
Ive Hermans
José Luis García Fierro
Juan A. Melero
Clara López-Aguado
Marta Paniagua
Jose Iglesias
Patrick Wolf
Blanca Hernández
Gabriel Morales
Source :
Green Chemistry. 18:5777-5781
Publication Year :
2016
Publisher :
Royal Society of Chemistry (RSC), 2016.

Abstract

The one-pot conversion of xylose into GVL in 2-propanol has been achieved over bifunctional Zr- and Al-containing beta zeolite catalysts, prepared via a post-synthetic route, possessing both Bronsted and Lewis functionalities. A GVL yield of 35 mol% was obtained at 190 °C after 48 h.

Details

ISSN :
14639270 and 14639262
Volume :
18
Database :
OpenAIRE
Journal :
Green Chemistry
Accession number :
edsair.doi...........fced56fa67cb35c976b2e225f3641129
Full Text :
https://doi.org/10.1039/c6gc01888b