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The Scales of Time, Length, Mass, Energy, and Other Fundamental Physical Quantities in the Atomic World and the Use of Atomic Units in Quantum Mechanical Calculations

Authors :
Wai-Kee Li
Boon K. Teo
Source :
Journal of Chemical Education. 88:921-928
Publication Year :
2011
Publisher :
American Chemical Society (ACS), 2011.

Abstract

This article is divided into two parts. In the first part, the atomic unit (au) system is introduced and the scales of time, space (length), and speed, as well as those of mass and energy, in the atomic world are discussed. In the second part, the utility of atomic units in quantum mechanical and spectroscopic calculations is illustrated with examples. It is shown that the system of atomic units can greatly facilitate calculations and unit conversions. In addition, a number of topics that can be fruitfully treated with the au system, including photoelectric effect, hydrogen atom and different Rydberg constants, positronium atom, atomic mass unit, nuclear binding energy, nuclear reaction energetics, annihilation and mass-energy interconversions, femtosecond and attosecond spectroscopies, quantum-size effects, excitons in semiconductors, and so forth are presented and discussed.

Details

ISSN :
19381328 and 00219584
Volume :
88
Database :
OpenAIRE
Journal :
Journal of Chemical Education
Accession number :
edsair.doi...........fc8c304459767a1c1faf5d5797b7fad1