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Asymmetric total syntheses of elaeokanines A and B via .alpha.-sulfinyl ketimine
- Source :
- The Journal of Organic Chemistry. 55:2128-2132
- Publication Year :
- 1990
- Publisher :
- American Chemical Society (ACS), 1990.
-
Abstract
- α-Lithiated (+)-(R)-4,5-dihydro-2-[[(4-methylphenyl)sulfinyl]methyl]-3H-pyrrole (4) underwent annulation with 1,3-diiodopropane to give (-)-(SS)-1,2,3,5,6,7-hexahydro-8-[(4-methylphenyl)sulfinyl]indolizine (6), which was converted into (-)-elaeokanine B (three steps) and (+)-elaeokanine A (four steps)
Details
- ISSN :
- 15206904 and 00223263
- Volume :
- 55
- Database :
- OpenAIRE
- Journal :
- The Journal of Organic Chemistry
- Accession number :
- edsair.doi...........fc2c50cbbdd864c1b9921c59bf488288
- Full Text :
- https://doi.org/10.1021/jo00294a028