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Crystal structure and thermoelectric properties of clathrate, Ba8Ni3.5Si42.0: Small cage volume and large disorder of the guest atom

Authors :
Tanghong Yi
Mike Orellana
Susan M. Kauzlarich
John H. Roudebush
Sabah K. Bux
Source :
Journal of Solid State Chemistry. 192:102-108
Publication Year :
2012
Publisher :
Elsevier BV, 2012.

Abstract

Samples with the type-I clathrate composition Ba{sub 8}Ni{sub x}Si{sub 46-x} have been synthesized and their structure and thermoelectric properties characterized. Microprobe analysis indicates the Ni incorporation to be 2.62{

Details

ISSN :
00224596
Volume :
192
Database :
OpenAIRE
Journal :
Journal of Solid State Chemistry
Accession number :
edsair.doi...........fc0d88a72c061be888821f8797ea7d63
Full Text :
https://doi.org/10.1016/j.jssc.2012.02.054