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Design of Lewis base functionalized ionic liquids for the N-formylation of amines with CO2 and hydrosilane: The cation effects
- Source :
- Catalysis Today. 356:563-569
- Publication Year :
- 2020
- Publisher :
- Elsevier BV, 2020.
-
Abstract
- A series of functionalized ionic liquids (ILs) were developed for the reductive functionalization of CO2 with amine and hydrosilane to afford formamides under mild conditions. It was found that 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)-based IL i.e. [DBUC12]Br showed high efficiency for the N-formylation reaction of amines without using any organic solvents or additives. Furthermore, control experiments suggested the cations with active hydrogen may weaken the nucleophilicity of anions through ion pairing interactions, thereby affecting the activation of hydrosilane. The reaction mechanism was then investigated by Density Functional Theory (DFT) calculations. This protocol represents a highly efficient and environmentally friendly example for catalytic conversion of CO2 into value-added chemicals such as formamide derivatives by employing DBU functionalized ILs.
- Subjects :
- Formamide
Reaction mechanism
02 engineering and technology
General Chemistry
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Combinatorial chemistry
Catalysis
0104 chemical sciences
Formylation
chemistry.chemical_compound
chemistry
Nucleophile
Ionic liquid
Amine gas treating
Lewis acids and bases
0210 nano-technology
Subjects
Details
- ISSN :
- 09205861
- Volume :
- 356
- Database :
- OpenAIRE
- Journal :
- Catalysis Today
- Accession number :
- edsair.doi...........fbf4489dc448e894f5ebe54e19666fa9