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Preparation and mechanical properties of strong and tough poly (vinyl alcohol)-polypeptide double-network hydrogels
- Source :
- European Polymer Journal. 99:504-510
- Publication Year :
- 2018
- Publisher :
- Elsevier BV, 2018.
-
Abstract
- Poly(vinyl alcohol) (PVA)-polypeptide double-network hydrogels with various ionic liquid (IL)-based polypeptides were prepared by a freezing/thawing method. Tensile tests revealed that the stiffness and toughness of the PVA hydrogels were significantly improved (e.g., 6.3 times the Young’s modulus and 5.8 times the work of extension) by incorporation of IL-based polypeptides. An optimized mechanical property was achieved by incorporation of α-helical imidazolium-based polypeptides at x = 0.03. Rheological tests revealed a thermally induced transition at 51.4–58.1 °C for the double network PVA/PPLG-ImBF4-x-67 (x = 0.01, 0.02, 0.03) hydrogels due to the rupture of the electrostatic interactions. Field emission scanning electron microscopy (FESEM) and wide-angle X-ray diffraction (WAXD) results suggested that the strong and tough double-network hydrogel was constructed by PVA crystallites and ionic bonds of IL-based polypeptide as the double physical cross-linkers.
- Subjects :
- Vinyl alcohol
Toughness
Materials science
Polymers and Plastics
Organic Chemistry
General Physics and Astronomy
Modulus
Ionic bonding
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
chemistry.chemical_compound
chemistry
Chemical engineering
Self-healing hydrogels
Ionic liquid
Ultimate tensile strength
Materials Chemistry
Crystallite
0210 nano-technology
Subjects
Details
- ISSN :
- 00143057
- Volume :
- 99
- Database :
- OpenAIRE
- Journal :
- European Polymer Journal
- Accession number :
- edsair.doi...........fab554c58714bbb7b55d57ec80d9d55e