Back to Search
Start Over
One-dimensional DABCO hydrogen-bonding chain in a hexagonal channel of magnetic [Ni(dmit)2]
- Source :
- Dalton Transactions. 49:16772-16777
- Publication Year :
- 2020
- Publisher :
- Royal Society of Chemistry (RSC), 2020.
-
Abstract
- Crystals of (HDABCO+)9(DABCO)[Ni(dmit)2]9·6CH3CN were shown to have a space group of R3[combining macron], a hexapetal flower-like channel of [Ni(dmit)2] anions, and a one-dimensional hydrogen bonding chain composed of protonated DABCO and CH3CN molecules. The crystals display antiferromagnetic and ferromagnetic interactions within and between hexamers, respectively, whereas the flexible DABCO-CH3CN array shows dielectric relaxation.
Details
- ISSN :
- 14779234 and 14779226
- Volume :
- 49
- Database :
- OpenAIRE
- Journal :
- Dalton Transactions
- Accession number :
- edsair.doi...........fa3ef07b4dca32e68795ef18dcb3c41e