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Direct S-Arylation of Unactivated Arylsulfoxides Using [Pd(IPr*)(cin)Cl]

Authors :
Anthony Chartoire
Frédéric Izquierdo
Steven P. Nolan
Source :
ACS Catalysis. 3:2190-2193
Publication Year :
2013
Publisher :
American Chemical Society (ACS), 2013.

Abstract

The direct S-arylation of unactivated arylsulfoxides catalyzed by [Pd(IPr*)(cin)Cl] is described. Several arylmethylsulfoxides were coupled to various aryl halides in moderate to good yields (17 examples, 34–85%). Scope, limitations, and reaction mechanism are discussed.

Subjects

Subjects :
chemistry.chemical_compound
Reaction mechanism
chemistry
Aryl
Organic chemistry
chemistry.chemical_element
Halide
Sulfoxide
General Chemistry
Catalysis
Palladium

Details

ISSN :
21555435
Volume :
3
Database :
OpenAIRE
Journal :
ACS Catalysis
Accession number :
edsair.doi...........f97db100f0c5a7b6f1a9cd410886d9d2

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Authors Abstract Subjects Details