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Relations between morphology and micromechanical properties of alpha, beta and gamma phases of iPP
- Source :
- Polymer Testing. 67:522-532
- Publication Year :
- 2018
- Publisher :
- Elsevier BV, 2018.
-
Abstract
- The relations between crystalline structure and micromechanical properties of α-, β- and γ-phase of isotactic polypropylene (iPP) were investigated. The iPP samples with various crystalline phase compositions were prepared by a controlled high-pressure crystallization that enabled us to obtain not only α-iPP and β-iPP modifications, but also a series of almost pure γ-iPP samples with gradually changing morphology, crystallinity and lamellar thickness. The micromechanical properties were assessed by instrumented microindentation hardness testing (MHI), from which we determined indentation hardness (HIT), indentation modulus (EIT), indentation creep (CIT) and elastic part of the indentation work (ηIT). It was demonstrated that γ-iPP does not necessarily exhibit better mechanical performance than α- and β-iPP, as suggested by some previous studies, because the final properties are strongly influenced not only by the phase composition (i.e. by the content of α-, β- and γ-phase), but also by the overall crystallinity.
- Subjects :
- Materials science
Polymers and Plastics
Organic Chemistry
Modulus
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Indentation hardness
0104 chemical sciences
law.invention
Crystallinity
Creep
law
Indentation
Phase (matter)
Lamellar structure
Composite material
Crystallization
0210 nano-technology
Subjects
Details
- ISSN :
- 01429418
- Volume :
- 67
- Database :
- OpenAIRE
- Journal :
- Polymer Testing
- Accession number :
- edsair.doi...........f92fd855587864477d90d3c21f68973a