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ChemInform Abstract: Rapid Synthesis of Isoquinolinones by Intramolecular Coupling of Amides and Ketones

Authors :
Yu Liu
Wen-Tao Wei
Ming Yan
Lin-miao Ye
Xue-jing Zhang
Rong-Hui Lei
Source :
ChemInform. 46
Publication Year :
2015
Publisher :
Wiley, 2015.

Abstract

Amides and ketones were intramolecularly coupled in the presence of KOt-Bu/DMF. The reaction provided good yields of a variety of isoquinolinones. A reaction mechanism of radical addition and subsequent E2-elimination is proposed.

Details

ISSN :
09317597
Volume :
46
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........f86298eaf815993d123cd1f32878b8a6
Full Text :
https://doi.org/10.1002/chin.201521178