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Applications and Extensions of Statistical Theories
- Source :
- Unimolecular Reaction Dynamics
- Publication Year :
- 1996
- Publisher :
- Oxford University Press, 1996.
-
Abstract
- The RRKM rate constant as given by equation (6.73) in the previous chapter is expressed as a ratio of the sum of states in the transition state and the density of states in the reactant molecule. An accurate calculation of this rate constant requires that all vibrational anharmonicity and vibrational/rotational coupling be included in calculating the sum and density.
- Subjects :
- Physics::Chemical Physics
Subjects
Details
- Database :
- OpenAIRE
- Journal :
- Unimolecular Reaction Dynamics
- Accession number :
- edsair.doi...........f6aa1c752be62ee7994f576dbdc76d3f
- Full Text :
- https://doi.org/10.1093/oso/9780195074949.003.0009