Back to Search
Start Over
Metallic layered germanium phosphide GeP5 for high rate flexible all-solid-state supercapacitors
- Source :
- Journal of Materials Chemistry A. 6:19409-19416
- Publication Year :
- 2018
- Publisher :
- Royal Society of Chemistry (RSC), 2018.
-
Abstract
- In this study, high quality GeP5 crystals with two-dimensional (2D) layered structures and novel electrical conductivity of 2.4 × 106 S m−1 have been prepared under high-temperature high-pressure oriented growth technique (HTHP-OGT). The as-synthesized GeP5 nanoflakes, after liquid phase exfoliation, show promising potential for application as electrode materials in all-solid-state supercapacitors (ASSPs). The as-prepared GeP5-ASSP exhibits excellent electrochemical performances, including an ultrahigh scan rate of 1000 V s−1, a high specific capacitance of up to 35.86 F cm−3 at 5 mV s−1, a great power density of 397.24 W cm−3 and an energy density of 4.98 mW h cm−3. Moreover, the device can retain 83.7% and 88% of the initial capacitance retention at 180° bending and after 10 000 cycles, respectively, showing outstanding flexibility and superior cycling stability. These properties indicate the promising application of the metallic layered GeP5 for flexible energy storage devices.
- Subjects :
- Horizontal scan rate
Supercapacitor
Materials science
Renewable Energy, Sustainability and the Environment
business.industry
Phosphide
chemistry.chemical_element
Germanium
02 engineering and technology
General Chemistry
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Capacitance
Exfoliation joint
Energy storage
0104 chemical sciences
chemistry.chemical_compound
chemistry
Electrical resistivity and conductivity
Optoelectronics
General Materials Science
0210 nano-technology
business
Subjects
Details
- ISSN :
- 20507496 and 20507488
- Volume :
- 6
- Database :
- OpenAIRE
- Journal :
- Journal of Materials Chemistry A
- Accession number :
- edsair.doi...........f6950f10b7f016560000c4e1a206a21d