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Dynamics and Response of Polymer-Coated Surface Acoustic Wave Devices: Effect of Viscoelastic Properties and Film Resonance

Authors :
Stephen D. Senturia
Gregory C. Frye
Stephen J. Martin
Source :
Analytical Chemistry. 66:2201-2219
Publication Year :
1994
Publisher :
American Chemical Society (ACS), 1994.

Abstract

The response of polymer-coated surface acoustic wave (SAW) devices to temperature changes and polymer vapor absorption is examined. A perturbational approach is used to relate velocity and attenuation responses to film translational and strain modes generated by the SAW. Two distinct regimes of film behavior arise, causing different SAW responses. For glassy films, displacement is nearly uniform across the film thickness, varying only in the direction of propagation. A model developed to predict velocity and attenuation in this regime (model 1), reduces to the familiar Tiersten (Wohltjen) equation for purely elastic films. For elastomeric (rubbery) films, inertial effects cause a phase lag to occur across the film for shear displacements. A model to account for these cross-film displacement gradients (model 2) predicts a characteristic resonant response when the film phase shift reaches n[pi]/2, where n is an odd integer. These model predictions are compared with measured responses from polyisobutylene-coated SAW devices as temperature is varied and during exposure to high vapor concentrations. 48 refs., 15 figs., 6 tabs.

Details

ISSN :
15206882 and 00032700
Volume :
66
Database :
OpenAIRE
Journal :
Analytical Chemistry
Accession number :
edsair.doi...........f653c5defbc1da4221ff40c01bf6f38d
Full Text :
https://doi.org/10.1021/ac00086a003